TosMIC

TosMIC^[1]

IUPAC name 1-(isocyanomethylsulfonyl)-4-methylbenzene
Identifiers
CAS number	36635-61-7
PubChem	161915
ChemSpider	142204^Y
Jmol-3D images	Image 1
SMILES O=S(=O)(c1ccc(cc1)C)C[N+]#[C-]
InChI InChI=1S/C9H9NO2S/c1-8-3-5-9(6-4-8)13(11,12)7-10-2/h3-6H,7H2,1H3^Y Key: CFOAUYCPAUGDFF-UHFFFAOYSA-N^Y InChI=1/C9H9NO2S/c1-8-3-5-9(6-4-8)13(11,12)7-10-2/h3-6H,7H2,1H3 Key: CFOAUYCPAUGDFF-UHFFFAOYAC
Properties
Molecular formula	C₉H₉NO₂S
Molar mass	195.24 g mol⁻¹
Melting point	109-113 °C, 382-386 K, 228-235 °F
Hazards
R-phrases	R23/24/25
S-phrases	S36/37 S45
Y (verify) (what is: Y/N?) Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
Infobox references

Toluenesulfonylmethyl isocyanide or TOSMIC is an organic compound with the formula CH₃C₆H₄SO₂CH₂NC. The molecule contains both sulfonyl and isocyanide groups. It is a colourless solid that unlike many isocyanides, is odorless. It is prepared by dehydration of the related formamide derivative.^[2]

References

^ p-Toluenesulfonylmethyl isocyanide at Sigma-Aldrich
^ B. E. Hoogenboom, O. H. Oldenziel, and A. M. van Leusen "Toluenesulfonylmethyl isocyanide" Organic Syntheses, Coll. Vol. 6, p.987 (1988).